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Issue 91, 2018
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A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

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Abstract

An exceedingly rare three-dimensional CO2-coordinated inorganic polyoxoanion was prepared by a hydrothermal synthesis reaction. The CO2 ligand connects with two Zn-ε-Keggin cores in a linear and symmetrical μ22o,o coordination pattern with a C[double bond, length as m-dash]O bond length of 1.099(112) Å. The new compound reported here exhibits not only appealing structures but also high catalytic activity for the cycloaddition of carbon dioxide with epoxides.

Graphical abstract: A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

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Publication details

The article was received on 30 Aug 2018, accepted on 26 Sep 2018 and first published on 26 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC07041E
Citation: Chem. Commun., 2018,54, 12808-12811
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    A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

    W. Cheng, Y. Xue, X. Luo and Y. Xu, Chem. Commun., 2018, 54, 12808
    DOI: 10.1039/C8CC07041E

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