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Tetrahedral metal-organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

Abstract

Tetrahedral FeII4L6 coordination cages containing well-designed linkers with rigid π-electron aromatic rings and flexible alkyl units were rationally constructed. Interestingly, these tetrahedral cages have rare cube-like cavities for selective encapsulation of fullerene guests. In addition, the solid state spin-crossover properties were influenced by guest binding of fullerene C60.

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Publication details

The article was received on 15 Aug 2018, accepted on 12 Oct 2018 and first published on 12 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC06652C
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Tetrahedral metal-organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

    W. Han, H. Zhang, Y. Wang, W. Liu, X. Yan, T. Li and Z. Gu, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC06652C

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