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Issue 89, 2018
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Tetrahedral metal–organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

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Abstract

Tetrahedral FeII4L6 coordination cages containing organic linkers with rigid π-electron aromatic rings and flexible alkyl units were constructed. Interestingly, these tetrahedral cages have rare cube-like cavities for selective encapsulation of fullerene guests. In addition, the solid state spin-crossover properties were influenced by guest binding of fullerene C60.

Graphical abstract: Tetrahedral metal–organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

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Publication details

The article was received on 15 Aug 2018, accepted on 12 Oct 2018 and first published on 12 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC06652C
Citation: Chem. Commun., 2018,54, 12646-12649
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    Tetrahedral metal–organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

    W. Han, H. Zhang, Y. Wang, W. Liu, X. Yan, T. Li and Z. Gu, Chem. Commun., 2018, 54, 12646
    DOI: 10.1039/C8CC06652C

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