Jump to main content
Jump to site search

Issue 84, 2018
Previous Article Next Article

The cyclo-Sb6 ring in the [Sb6(RuCp*)2]2− ion

Author affiliations

Abstract

The [Sb6(RuCp*)2]2− (1) anion represents the first example of a Zintl cluster with a boat-like cyclo-Sb6 subunit and the first ruthenium polyantimonide complex. The anion is dynamic in solution and fragments in the gas phase. Structural parameters and DFT calculations suggest the possibility of Sb[double bond, length as m-dash]Sb double bond character.

Graphical abstract: The cyclo-Sb6 ring in the [Sb6(RuCp*)2]2− ion

Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Aug 2018, accepted on 26 Sep 2018 and first published on 26 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06542J
Citation: Chem. Commun., 2018,54, 11917-11920
  •   Request permissions

    The cyclo-Sb6 ring in the [Sb6(RuCp*)2]2− ion

    Y. Wang, P. Zavalij and B. Eichhorn, Chem. Commun., 2018, 54, 11917
    DOI: 10.1039/C8CC06542J

Search articles by author

Spotlight

Advertisements