Barium-catalyzed C–OH/P–H dehydrative cross-coupling for C–P bond construction

Xiangyang Wo; Peizhong Xie; Weishan Fu; Cuiqing Gao; Yanan Liu; Zuolian Sun; Teck-Peng Loh

doi:10.1039/C8CC06530F

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Barium-catalyzed C–OH/P–H dehydrative cross-coupling for C–P bond construction†

Xiangyang Wo,^a Peizhong Xie,

*^a Weishan Fu,^a Cuiqing Gao,^b Yanan Liu,^a Zuolian Sun^a and Teck-Peng Loh

*^ac

Author affiliations

* Corresponding authors

^a School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, P. R. China
E-mail: peizhongxie@njtech.edu.cn, teckpeng@ntu.edu.sg

^b Co-Innovation Center for the Sustainable Forestry in Southern China, College of Forestry, Nanjing Forestry University, Nanjing, China

^c Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
E-mail: teckpeng@ntu.edu.sg

Abstract

A barium-catalyzed C–OH/P–H dehydrative cross-coupling protocol for the construction of C–P bonds was developed. This reaction was performed in an environmentally benign manner with water as the only by-product. A variety of allylic phosphorus compounds can be isolated in good to excellent yields.

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Article information

DOI: https://doi.org/10.1039/C8CC06530F
Article type: Communication
Submitted: 10 Aug 2018
Accepted: 11 Sep 2018
First published: 12 Sep 2018

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Chem. Commun., 2018,54, 11132-11135

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Barium-catalyzed C–OH/P–H dehydrative cross-coupling for C–P bond construction

X. Wo, P. Xie, W. Fu, C. Gao, Y. Liu, Z. Sun and T. Loh, Chem. Commun., 2018, 54, 11132 DOI: 10.1039/C8CC06530F

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Chemical Communications

Barium-catalyzed C–OH/P–H dehydrative cross-coupling for C–P bond construction†

Abstract

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Barium-catalyzed C–OH/P–H dehydrative cross-coupling for C–P bond construction

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