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Issue 78, 2018
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Metallaaromatic biaryl atropisomers

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Synthesis of stable irida-binaphthyl and -phenanthryl complexes, the first examples of metallaaromatic biaryl atropisomers, has been achieved. The combination of experimental and theoretical studies revealed that the nature of these systems is comparable to that of well-known 1,1′-binaphthalene both in terms of aromaticity and atropisomerism.

Graphical abstract: Metallaaromatic biaryl atropisomers

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The article was received on 07 Aug 2018, accepted on 06 Sep 2018 and first published on 07 Sep 2018

Article type: Communication
DOI: 10.1039/C8CC06443A
Chem. Commun., 2018,54, 10974-10976

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    Metallaaromatic biaryl atropisomers

    M. Talavera, A. Peña-Gallego, J. L. Alonso-Gómez and S. Bolaño, Chem. Commun., 2018, 54, 10974
    DOI: 10.1039/C8CC06443A

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