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Issue 88, 2018
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Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

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Abstract

Here, we report a facile procedure based on surface self-assembly for controlling the π–π stacking order and relevant rectified charge transport properties in stacks of aromatic molecules on a single-molecule scale. A high rectification ratio of 10 was achieved and the rectification direction was uniquely determined by the controlled stacking order of the aromatic molecules on the graphene layers of HOPG.

Graphical abstract: Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

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Article information


Submitted
07 Aug 2018
Accepted
24 Sep 2018
First published
25 Sep 2018

Chem. Commun., 2018,54, 12443-12446
Article type
Communication

Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

M. Iwane, T. Tada, T. Osuga, T. Murase, M. Fujita, T. Nishino, M. Kiguchi and S. Fujii, Chem. Commun., 2018, 54, 12443
DOI: 10.1039/C8CC06430J

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