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Issue 88, 2018
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Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

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Abstract

Here, we report a facile procedure based on surface self-assembly for controlling the π–π stacking order and relevant rectified charge transport properties in stacks of aromatic molecules on a single-molecule scale. A high rectification ratio of 10 was achieved and the rectification direction was uniquely determined by the controlled stacking order of the aromatic molecules on the graphene layers of HOPG.

Graphical abstract: Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

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Publication details

The article was received on 07 Aug 2018, accepted on 24 Sep 2018 and first published on 25 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06430J
Citation: Chem. Commun., 2018,54, 12443-12446
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    Controlling stacking order and charge transport in π-stacks of aromatic molecules based on surface assembly

    M. Iwane, T. Tada, T. Osuga, T. Murase, M. Fujita, T. Nishino, M. Kiguchi and S. Fujii, Chem. Commun., 2018, 54, 12443
    DOI: 10.1039/C8CC06430J

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