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Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(IV)

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Abstract

A dinuclear, butadiene-bridged complex, trans222-1,3-butadiene-bis(trichloroplatinate(II)) (1) was unexpectedly obtained on photolysis of acetone solutions of (NBu4)2[PtCl6].

Graphical abstract: Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(iv)

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Publication details

The article was received on 07 Aug 2018, accepted on 01 Nov 2018 and first published on 02 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC06423G
Citation: Chem. Commun., 2018, Advance Article
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    Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(IV)

    I. H. Silalahi, N. K. Sethi, M. Z. Shafikov, V. Chechik, A. C. Whitwood and D. W. Bruce, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC06423G

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