Issue 87, 2018
From the journal:

Chemical Communications

Palladium-catalysed magnesiation of benzene†

Martí Garçon, ORCID logo a   Andrew J. P. Whitea  and  Mark R. Crimmin ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: m.crimmin@imperial.ac.uk

Abstract

In the presence of a catalytic quantity of [Pd(PCy3)2], a reagent containing a Mg–Mg bond effects the C–H functionalisation of benzene resulting in a 100% atom efficient transformation to generate an unprecedented aryl magnesium hydride.

Graphical abstract: Palladium-catalysed magnesiation of benzene

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Article information

DOI
https://doi.org/10.1039/C8CC06392C
Article type
Communication
Submitted
06 Aug 2018
Accepted
08 Oct 2018
First published
08 Oct 2018

Chem. Commun., 2018,54, 12326-12328

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Palladium-catalysed magnesiation of benzene

M. Garçon, A. J. P. White and M. R. Crimmin, Chem. Commun., 2018, 54, 12326 DOI: 10.1039/C8CC06392C

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