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Triazole-bearing calixpyrroles: strong halide binding affinities through multiple N–H and C–H hydrogen bonds

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Abstract

Triazole-bearing calixpyrroles (TCPs) were synthesized as artificial anion binding receptors. The additional C–H⋯X hydrogen bonding interaction induced strong binding affinity towards halide ions. Using this strong binding affinity, Cl was successfully extracted from the aqueous to organic phase.

Graphical abstract: Triazole-bearing calixpyrroles: strong halide binding affinities through multiple N–H and C–H hydrogen bonds

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Publication details

The article was received on 06 Aug 2018, accepted on 03 Sep 2018 and first published on 04 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06385K
Citation: Chem. Commun., 2018, Advance Article
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    Triazole-bearing calixpyrroles: strong halide binding affinities through multiple N–H and C–H hydrogen bonds

    H. Kim, K. Hong, J. H. Lee, P. Kang, M. Choi and W. Jang, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC06385K

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