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Issue 74, 2018
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Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates

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Abstract

The first example of hydrogen evolution reactivity (HER) of lanthanide-functionalized Keggin-based polyoxotungstates under photochemical and electrochemical conditions is reported. The HER activity under homogeneous, visible light-driven conditions and under heterogeneous, electrochemical conditions depends on the type of lanthanide functionalization, so that a new class of model HER catalysts for systematic reactivity studies is now accessible.

Graphical abstract: Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates

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Article information


Submitted
03 Aug 2018
Accepted
23 Aug 2018
First published
23 Aug 2018

Chem. Commun., 2018,54, 10427-10430
Article type
Communication

Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates

M. Arab Fashapoyeh, M. Mirzaei, H. Eshtiagh-Hosseini, A. Rajagopal, M. Lechner, R. Liu and C. Streb, Chem. Commun., 2018, 54, 10427
DOI: 10.1039/C8CC06334F

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