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Sensing the chirality of various organic solvents by helically arranged π-blades

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Abstract

Although the chiral enrichment of dynamic prochiral molecules usually requires a strong interaction with a chiral source, the enantiomer ratio of a propeller-shaped molecule, obtained by a recently developed boron-mediated benzannulation reaction of alkynes, is biased in various organic solvents through solvation for the propeller moieties.

Graphical abstract: Sensing the chirality of various organic solvents by helically arranged π-blades

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Publication details

The article was received on 01 Aug 2018, accepted on 10 Sep 2018 and first published on 10 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06277C
Citation: Chem. Commun., 2018, Advance Article
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    Sensing the chirality of various organic solvents by helically arranged π-blades

    Y. Shimizu, Y. Shoji, D. Hashizume, Y. Nagata and T. Fukushima, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC06277C

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