Issue 83, 2018
From the journal:

Chemical Communications

Expedient stereospecific Co-catalyzed tandem C–N and C–O bond formation of N-methylanilines with styrene oxides†

Vanaparthi Satheesh,a   Sundaravel Vivek Kumar ORCID logo a  and  Tharmalingam Punniyamurthy ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India
E-mail: tpunni@iitg.ac.in

Abstract

Cobalt(II)-catalyzed stereospecific coupling of N-methylanilines with styrene oxides is developed via tandem C–N and C–O bond formation using tert-butyl hydroperoxide (TBHP) as an oxidant. Optically active epoxide can be reacted with high optical purity.

Graphical abstract: Expedient stereospecific Co-catalyzed tandem C–N and C–O bond formation of N-methylanilines with styrene oxides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC06223D
Article type
Communication
Submitted
31 Jul 2018
Accepted
17 Sep 2018
First published
18 Sep 2018

Chem. Commun., 2018,54, 11813-11816

Permissions

Request permissions

Expedient stereospecific Co-catalyzed tandem C–N and C–O bond formation of N-methylanilines with styrene oxides

V. Satheesh, S. Vivek Kumar and T. Punniyamurthy, Chem. Commun., 2018, 54, 11813 DOI: 10.1039/C8CC06223D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements