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Issue 72, 2018
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Transition-metal-free synthesis of vicinal triborated compounds and selective functionalisation of the internal C–B bond

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Abstract

1,2,3-Triborated compounds can be prepared by simple nucleophilic borylation of 1,3-dienes, without the assistance of metal catalysts. Selective functionalisation of the internal C–B bond of the 1,2,3-triborated compounds, through cross-coupling with aryl iodides, highlights the powerful methodology toward polyfunctionalisation.

Graphical abstract: Transition-metal-free synthesis of vicinal triborated compounds and selective functionalisation of the internal C–B bond

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Publication details

The article was received on 28 Jul 2018, accepted on 10 Aug 2018 and first published on 10 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC06153J
Citation: Chem. Commun., 2018,54, 10104-10107
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    Transition-metal-free synthesis of vicinal triborated compounds and selective functionalisation of the internal C–B bond

    E. Davenport and E. Fernandez, Chem. Commun., 2018, 54, 10104
    DOI: 10.1039/C8CC06153J

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