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Issue 76, 2018
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Palladium-catalyzed aerobic oxidative carbonylation of alkynes with amines: a general access to substituted maleimides

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Abstract

A catalytic oxidative carbonylation reaction was developed for the synthesis of polysubstituted maleimides from alkynes and amines with air as a green oxidant. This novel transformation proceeds in the presence of palladium chloride without the need for expensive ligands or additives and has a broad substrate scope affording a variety of maleimides in good to high yields.

Graphical abstract: Palladium-catalyzed aerobic oxidative carbonylation of alkynes with amines: a general access to substituted maleimides

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Publication details

The article was received on 17 Jul 2018, accepted on 30 Aug 2018 and first published on 30 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05802D
Citation: Chem. Commun., 2018,54, 10710-10713
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    Palladium-catalyzed aerobic oxidative carbonylation of alkynes with amines: a general access to substituted maleimides

    J. Yang, J. Liu, R. Jackstell and M. Beller, Chem. Commun., 2018, 54, 10710
    DOI: 10.1039/C8CC05802D

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