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Organosoluble tetravalent actinide di- and trifluorides

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Abstract

Soluble molecular actinide(IV) fluorides can be prepared in high yield via redox or metathesis reactions of silver fluorides with actinide compounds containing ancillary iodide or fluorinated thiolate ligands. Two compounds, (py)4UF2I2·2py and (py)7Th2F5(SC6F5)3·2py were isolated and characterized by conventional methods, powder and low temperature single crystal X-ray diffraction.

Graphical abstract: Organosoluble tetravalent actinide di- and trifluorides

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Publication details

The article was received on 09 Jul 2018, accepted on 02 Oct 2018 and first published on 10 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC05501G
Citation: Chem. Commun., 2018, Advance Article
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    Organosoluble tetravalent actinide di- and trifluorides

    G. Gotthelf, M. A. Stuber, A. Y. Kornienko, T. J. Emge and J. G. Brennan, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC05501G

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