Jump to main content
Jump to site search

Issue 85, 2018
Previous Article Next Article

Organosoluble tetravalent actinide di- and trifluorides

Author affiliations

Abstract

Soluble molecular actinide(IV) fluorides can be prepared in high yield via redox or metathesis reactions of silver fluorides with actinide compounds containing ancillary iodide or fluorinated thiolate ligands. Two compounds, (py)4UF2I2·2py and (py)7Th2F5(SC6F5)3·2py were isolated and characterized by conventional methods, powder and low temperature single crystal X-ray diffraction.

Graphical abstract: Organosoluble tetravalent actinide di- and trifluorides

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Jul 2018, accepted on 02 Oct 2018 and first published on 10 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC05501G
Citation: Chem. Commun., 2018,54, 12018-12020
  •   Request permissions

    Organosoluble tetravalent actinide di- and trifluorides

    G. Gotthelf, M. A. Stuber, A. Y. Kornienko, T. J. Emge and J. G. Brennan, Chem. Commun., 2018, 54, 12018
    DOI: 10.1039/C8CC05501G

Search articles by author

Spotlight

Advertisements