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Actinide-Transition Metal Bonding in Heterobimetallic Uranium- and Thorium-Molybdenum Paddlewheel Complexes

Abstract

We report the preparation of four heterobimetallic uranium- and thorium-molybdenum paddlewheel complexes. The characterisation data calculations suggest the presence of Mo→An σ-interactions in all cases. These complexes represent unprecedented actinide-group 6 metal-metal bonds, where before heterobimetallic uranium-metal bonds were restricted to group 7-11 metals.

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Publication details

The article was received on 30 Jun 2018, accepted on 07 Nov 2018 and first published on 09 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC05268A
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Actinide-Transition Metal Bonding in Heterobimetallic Uranium- and Thorium-Molybdenum Paddlewheel Complexes

    A. Ayres, M. Zegke, J. Ostrowski, F. Tuna, E. J. L. McInnes, A. Wooles and S. Liddle, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC05268A

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