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Issue 71, 2018
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Visible-light promoted fluoroalkylselenolation: toward the reactivity of unsaturated compounds

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Abstract

The reactivity of fluoroalkylselenotoluenesulfonates with unsaturated substrates is explored herein. The direct activation of these shelf-stable reagents under visible light allows the double functionalisation of alkenes or alkynes efficiently, leading to a wide range of β-fluoroalkylselenolated sulfones. Mechanistic investigations have been undertaken supporting the formation of radical intermediates.

Graphical abstract: Visible-light promoted fluoroalkylselenolation: toward the reactivity of unsaturated compounds

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Article information


Submitted
30 Jun 2018
Accepted
06 Aug 2018
First published
06 Aug 2018

Chem. Commun., 2018,54, 9909-9912
Article type
Communication

Visible-light promoted fluoroalkylselenolation: toward the reactivity of unsaturated compounds

C. Ghiazza, L. Khrouz, C. Monnereau, T. Billard and A. Tlili, Chem. Commun., 2018, 54, 9909
DOI: 10.1039/C8CC05256E

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