Jump to main content
Jump to site search


Molecular hydrides of divalent ytterbium supported by a macrocyclic ligand: synthesis, structure and olefin hydrofunctionalization catalysis

Abstract

BIS(TRIPHENYLSILYL) AND DIBENZYL YTTERBIUM(II) COMPLEXES SUPPORTED BY THE MACROCYCLIC POLYAMINE LIGAND ME4TACD (1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) REACTED WITH H2 TO GIVE THE CATIONIC YTTERBIUM HYDRIDES [(ME4TACD)2YB2(µ2 H)(2+N)](2-N)+ (N = 0,1). THE HYDRIDES CATALYZED THE H2/D2 ISOTOPE EXCHANGE AS WELL AS HYDROGENATION AND HYDROSILYLATION OF 1-HEXENE.

Back to tab navigation

Supplementary files

Publication details

The article was received on 27 Jun 2018, accepted on 11 Sep 2018 and first published on 12 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC05152F
Citation: Chem. Commun., 2018, Accepted Manuscript
  •   Request permissions

    Molecular hydrides of divalent ytterbium supported by a macrocyclic ligand: synthesis, structure and olefin hydrofunctionalization catalysis

    J. Okuda, T. P. Spaniol, L. Maron, D. Schuhknecht and K. Truong, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC05152F

Search articles by author

Spotlight

Advertisements