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Issue 70, 2018
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Strong carbon cage influence on the single molecule magnetism in Dy–Sc nitride clusterfullerenes

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Abstract

Magnetic properties of endohedral metallofullerenes with nitride clusters DySc2N and Dy2ScN and different carbon cages are studied by SQUID magnetometry. All molecules behave as single molecule magnets (SMMs) and exhibit magnetic hysteresis. It is found that the blocking temperature of magnetization and relaxation times strongly depend on the fullerene cage, with the C80-Ih isomer offering the best SMM properties.

Graphical abstract: Strong carbon cage influence on the single molecule magnetism in Dy–Sc nitride clusterfullerenes

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Publication details

The article was received on 24 Jun 2018, accepted on 24 Jul 2018 and first published on 24 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC05029E
Citation: Chem. Commun., 2018,54, 9730-9733
  • Open access: Creative Commons BY license
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    Strong carbon cage influence on the single molecule magnetism in Dy–Sc nitride clusterfullerenes

    C. Schlesier, L. Spree, A. Kostanyan, R. Westerström, A. Brandenburg, A. U. B. Wolter, S. Yang, T. Greber and A. A. Popov, Chem. Commun., 2018, 54, 9730
    DOI: 10.1039/C8CC05029E

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