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Issue 61, 2018
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Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

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Abstract

Crystallographic, emission and NMR studies of a series of C3-symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb(III) and Eu(III) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudocontact NMR shifts and emission spectral profiles, giving new guidance for responsive NMR and spectral probe design.

Graphical abstract: Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

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Article information


Submitted
22 Jun 2018
Accepted
10 Jul 2018
First published
10 Jul 2018

Chem. Commun., 2018,54, 8486-8489
Article type
Communication

Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

K. Mason, A. C. Harnden, C. W. Patrick, A. W. J. Poh, A. S. Batsanov, E. A. Suturina, M. Vonci, E. J. L. McInnes, N. F. Chilton and D. Parker, Chem. Commun., 2018, 54, 8486
DOI: 10.1039/C8CC04995E

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