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Issue 63, 2018
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Copper-mediated intramolecular aminofluorination of 1,3-dienes by using nucleophilic fluorine reagents

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Abstract

A copper-mediated intramolecular aminofluorination of 1,3-dienes is disclosed, in which both AgF and Et3N·3HF can be used as the fluorine source. This protocol provides a variety of pyrrolidines bearing allylic fluorides with excellent regioselectivities and good diastereoselectivities.

Graphical abstract: Copper-mediated intramolecular aminofluorination of 1,3-dienes by using nucleophilic fluorine reagents

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Publication details

The article was received on 20 Jun 2018, accepted on 11 Jul 2018 and first published on 11 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC04909B
Citation: Chem. Commun., 2018,54, 8709-8712
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    Copper-mediated intramolecular aminofluorination of 1,3-dienes by using nucleophilic fluorine reagents

    Z. Zhang, P. Chen and G. Liu, Chem. Commun., 2018, 54, 8709
    DOI: 10.1039/C8CC04909B

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