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Issue 79, 2018
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Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

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Abstract

A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.

Graphical abstract: Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

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Publication details

The article was received on 14 Jun 2018, accepted on 12 Sep 2018 and first published on 13 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC04780D
Citation: Chem. Commun., 2018,54, 11192-11195
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    Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

    A. Tahara, Y. Sunada, T. Takeshita, R. Inoue and H. Nagashima, Chem. Commun., 2018, 54, 11192
    DOI: 10.1039/C8CC04780D

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