Issue 79, 2018
From the journal:

Chemical Communications

Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds†

Atsushi Tahara, ORCID logo a   Yusuke Sunada, ORCID logo ab   Takashi Takeshita,c   Ryoko Inouec  and  Hideo Nagashima ORCID logo *ac  

* Corresponding authors

a Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
E-mail: nagasima@cm.kyushu-u.ac.jp

b Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan

c Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, Kasuga, Fukuoka 816-8580, Japan

Abstract

A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.

Graphical abstract: Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/C8CC04780D
Article type
Communication
Submitted
14 Jun 2018
Accepted
12 Sep 2018
First published
13 Sep 2018

Chem. Commun., 2018,54, 11192-11195

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Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

A. Tahara, Y. Sunada, T. Takeshita, R. Inoue and H. Nagashima, Chem. Commun., 2018, 54, 11192 DOI: 10.1039/C8CC04780D

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