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Metal coordination induced ring contraction of porphyrin derivatives

Abstract

A remarkable rearrangement of a diferrocenylporphyrin to give a silver(III) corrole has been discovered. Compared to the previously reported porphyrin to corrole ring conversions (extremely rare and poor reaction yields), our methodology delivers near quantitative yield for this ring contraction.

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Publication details

The article was received on 12 Jun 2018, accepted on 09 Aug 2018 and first published on 09 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC04670K
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Metal coordination induced ring contraction of porphyrin derivatives

    B. Patra, S. Sobottka, S. Mondal, B. Sarkar and S. Kar, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC04670K

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