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Issue 72, 2018
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Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

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Abstract

A new family of mononuclear lanthanide complexes, where the eight coordinate lanthanide ions adopt a very rare cubic coordination geometry is reported. The Dy analogue exhibits SMM behavior with a Ueff value 95.7 K under a 0.02 T applied dc field. Ab initio calculations support the observed magnetic behavior.

Graphical abstract: Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

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Publication details

The article was received on 08 Jun 2018, accepted on 08 Aug 2018 and first published on 09 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC04565H
Citation: Chem. Commun., 2018,54, 10136-10139
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    Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

    D. I. Alexandropoulos, K. A. Schulte, K. R. Vignesh and K. R. Dunbar, Chem. Commun., 2018, 54, 10136
    DOI: 10.1039/C8CC04565H

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