Jump to main content
Jump to site search

Issue 56, 2018
Previous Article Next Article

Charge effects regulate reversible CO2 reduction catalysis

Author affiliations

Abstract

Modular but geometrically constrained ligands were used to investigate the impact of key ligand design parameters (charge and bite angle) on CO2 hydrogenation and formic acid dehydrogenation activity. These studies yielded an optimized catalyst that achieved over 118 000 turnovers in CO2 hydrogenation, 247 000 turnovers in HCO2H dehydrogenation, was applied in a hydrogen storage device used for 6 cycles of hydrogen storage/release without requiring changes in pH or solvent, and generated H2/CO2 gas at a pressure of 190 atm from formic acid.

Graphical abstract: Charge effects regulate reversible CO2 reduction catalysis

Back to tab navigation

Supplementary files

Article information


Submitted
31 May 2018
Accepted
18 Jun 2018
First published
26 Jun 2018

Chem. Commun., 2018,54, 7790-7793
Article type
Communication
Author version available

Charge effects regulate reversible CO2 reduction catalysis

J. B. Geri, J. L. Ciatti and N. K. Szymczak, Chem. Commun., 2018, 54, 7790
DOI: 10.1039/C8CC04370A

Social activity

Search articles by author

Spotlight

Advertisements