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Issue 68, 2018
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Substrate involvement in dioxygen bond dissociation catalysed by iron phthalocyanine supported on Ag(100)

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Abstract

Dioxygen adsorbs in the end-on configuration on-top of the Fe atoms of an iron phthalocyanine monolayer supported on Ag(100) and is partly cleaved at room temperature to produce O/FePc/Ag(100). Scanning tunnelling microscopy coupled to density functional theory calculations gives the first experimental evidence of the substrate involvement in the O2 bond dissociation.

Graphical abstract: Substrate involvement in dioxygen bond dissociation catalysed by iron phthalocyanine supported on Ag(100)

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Article information


Submitted
31 May 2018
Accepted
31 Jul 2018
First published
31 Jul 2018

Chem. Commun., 2018,54, 9418-9421
Article type
Communication

Substrate involvement in dioxygen bond dissociation catalysed by iron phthalocyanine supported on Ag(100)

F. Sedona, M. Lo Cicero, S. Carlotto, A. Basagni, M. M. S. Fakhrabadi, M. Casarin and M. Sambi, Chem. Commun., 2018, 54, 9418
DOI: 10.1039/C8CC04362K

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