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Issue 64, 2018
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Three-dimensional hydrogen bonding between Landers and planar molecules facilitated by electrostatic interactions with Ni adatoms

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Abstract

Using a combination of UHV-STM and molecular mechanics calculations, we investigate the surface self-assembly of a complex multi-component metal-molecule system with synergistic non-covalent interactions. Hydrogen bonding between three-dimensional Lander-DAT molecules and planar PTCDI molecules, adsorbed closer to the surface, is found to be facilitated by electrostatic interactions between co-adsorbed Ni adatoms and the flexible molecular DAT groups.

Graphical abstract: Three-dimensional hydrogen bonding between Landers and planar molecules facilitated by electrostatic interactions with Ni adatoms

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Article information


Submitted
28 May 2018
Accepted
13 Jul 2018
First published
16 Jul 2018

Chem. Commun., 2018,54, 8845-8848
Article type
Communication

Three-dimensional hydrogen bonding between Landers and planar molecules facilitated by electrostatic interactions with Ni adatoms

M. Yu, Y. Benjalal, C. Chen, N. Kalashnyk, W. Xu, R. Barattin, S. Nagarajan, E. Lægsgaard, I. Stensgaard, M. Hliwa, A. Gourdon, F. Besenbacher, X. Bouju and T. R. Linderoth, Chem. Commun., 2018, 54, 8845
DOI: 10.1039/C8CC04247K

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