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Issue 63, 2018
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Diastereoselective self-assembly of bisheptahelicene on Cu(111)

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Abstract

Stereochemical effects during two-dimensional crystallization of bisheptahelicene diastereomers on a Cu(111) surface have been studied with scanning tunnelling microscopy. The (M,M)- and (P,P)-enantiomers crystallize into a monolayer racemate lattice, whereas the (M,P)-diastereomers aggregate into their own monolayer phase.

Graphical abstract: Diastereoselective self-assembly of bisheptahelicene on Cu(111)

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Submitted
24 May 2018
Accepted
17 Jul 2018
First published
17 Jul 2018

Chem. Commun., 2018,54, 8757-8760
Article type
Communication

Diastereoselective self-assembly of bisheptahelicene on Cu(111)

A. Mairena, M. Parschau, J. Seibel, M. Wienke, D. Rentsch, A. Terfort and K. Ernst, Chem. Commun., 2018, 54, 8757
DOI: 10.1039/C8CC04160A

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