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Issue 74, 2018
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α-Arylation of alkylamines with sulfonylarenes through a radical chain mechanism

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Abstract

In the presence of a substoichiometric amount of a tert-butoxy radical precursor, the reaction of alkylamines with sulfonylarenes was found to give α-arylated alkylamines through homolytic aromatic substitution, where a radical chain is operative.

Graphical abstract: α-Arylation of alkylamines with sulfonylarenes through a radical chain mechanism

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Publication details

The article was received on 04 May 2018, accepted on 21 Aug 2018 and first published on 21 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC03604G
Citation: Chem. Commun., 2018,54, 10471-10474

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    α-Arylation of alkylamines with sulfonylarenes through a radical chain mechanism

    Y. Ikeda, R. Ueno, Y. Akai and E. Shirakawa, Chem. Commun., 2018, 54, 10471
    DOI: 10.1039/C8CC03604G

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