Issue 45, 2018
From the journal:

Chemical Communications

Synthons for carbide complex chemistry†

Anders Reinholdt, ORCID logo *ab   Anthony F. Hill ORCID logo b  and  Jesper Bendix ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
E-mail: a.reinholdt@chem.ku.dk, bendix@kiku.dk

b Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, Australia

Abstract

The sterically accessible carbide complex, (Cy3P)Cl3Ru[triple bond, length as m-dash]C–PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

Graphical abstract: Synthons for carbide complex chemistry

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC03596B
Article type
Communication
Submitted
04 May 2018
Accepted
11 May 2018
First published
11 May 2018

Chem. Commun., 2018,54, 5708-5711

Permissions

Request permissions

Synthons for carbide complex chemistry

A. Reinholdt, A. F. Hill and J. Bendix, Chem. Commun., 2018, 54, 5708 DOI: 10.1039/C8CC03596B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements