A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface

Chun-Rong Ye; Ji Zheng; Mian Li; Xiao-Chun Huang

doi:10.1039/C8CC03484B

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A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface†

Chun-Rong Ye,^a Ji Zheng,^a Mian Li

*^a and Xiao-Chun Huang

*^a

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* Corresponding authors

^a Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, China
E-mail: mli@stu.edu.cn, xchuang@stu.edu.cn
Fax: +86 0754-82902767

Abstract

The title MOF features a potential uninodal zeolite net, uks, which has never been found for real zeolites or zeolite-like MOFs. This rare structure exhibits specific anion binding of N₃⁻ over SCN⁻ in water, which reverses the Hofmeister series.

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DOI: https://doi.org/10.1039/C8CC03484B
Article type: Communication
Submitted: 30 Apr 2018
Accepted: 16 Jul 2018
First published: 16 Jul 2018

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Chem. Commun., 2018,54, 8769-8772

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A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface

C. Ye, J. Zheng, M. Li and X. Huang, Chem. Commun., 2018, 54, 8769 DOI: 10.1039/C8CC03484B

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Chemical Communications

A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface†

Abstract

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A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface

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