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Issue 65, 2018
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On the decoupling of molecules at metal surfaces

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Abstract

We report a method to achieve physical and electronic decoupling of organic molecules from a metal surface. Oxygen adsorbed on the Cu(100) surface immobilizes the surface electrons in the Cu–O covalent bonds. This results in electronic surface hardening and prevents charge transfer from the metal into perylene-tetracarboxylic dianhydride molecules subsequently deposited on this surface.

Graphical abstract: On the decoupling of molecules at metal surfaces

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Article information


Submitted
25 Apr 2018
Accepted
13 Jul 2018
First published
16 Jul 2018

Chem. Commun., 2018,54, 9039-9042
Article type
Communication

On the decoupling of molecules at metal surfaces

X. Yang, I. Krieger, D. Lüftner, S. Weiß, T. Heepenstrick, M. Hollerer, P. Hurdax, G. Koller, M. Sokolowski, P. Puschnig, M. G. Ramsey, F. S. Tautz and S. Soubatch, Chem. Commun., 2018, 54, 9039
DOI: 10.1039/C8CC03334J

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