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Issue 51, 2018
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Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

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Abstract

The use of a dodecanuclear zirconium acetate cluster as a precursor enables the rapid, clean mechanochemical synthesis of high-microporosity metal–organic frameworks NU-901 and UiO-67, with surface areas up to 2250 m2 g−1. Real-time X-ray diffraction monitoring reveals that mechanochemical reactions involving the conventional hexanuclear zirconium methacrylate precursor are hindered by the formation of an inert intermediate, which does not appear when using the dodecanuclear acetate cluster as a reactant.

Graphical abstract: Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

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Supplementary files

Article information


Submitted
19 Apr 2018
Accepted
23 May 2018
First published
23 May 2018

Chem. Commun., 2018,54, 6999-7002
Article type
Communication
Author version available

Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

A. M. Fidelli, B. Karadeniz, A. J. Howarth, I. Huskić, L. S. Germann, I. Halasz, M. Etter, S. Moon, R. E. Dinnebier, V. Stilinović, O. K. Farha, T. Friščić and K. Užarević, Chem. Commun., 2018, 54, 6999
DOI: 10.1039/C8CC03189D

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