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Issue 61, 2018
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[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

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Abstract

In this work, we examine the use of competitive 13C kinetic isotope effects (13C KIEs) on CO2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13C KIE measurements and theoretical calculations methodology for probing CO2 conversion reactions.

Graphical abstract: [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

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The article was received on 15 Apr 2018, accepted on 06 Jul 2018 and first published on 07 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC03009J
Citation: Chem. Commun., 2018,54, 8518-8521
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    [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

    T. W. Schneider, M. T. Hren, M. Z. Ertem and A. M. Angeles-Boza, Chem. Commun., 2018, 54, 8518
    DOI: 10.1039/C8CC03009J

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