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Issue 48, 2018
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A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

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Abstract

The reaction of [Cr3IIIO(OAc)6(H2O)3]NO3·AcOH with 2-hydroxynaphthaldehyde, 2-amino-isobutyric acid and NiCl2·6H2O in MeOH, under basic and solvothermal conditions, led to the formation of the quasi-1D coordination polymer {[CrIII2NiII(L)4(MeOH)2]}n (where L = the dianion of the Schiff base between 2-hydroxynaphthaldehyde and 2-amino-isobutyric acid), which behaves as a ferromagnetic chain, displaying slow relaxation of magnetization.

Graphical abstract: A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

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Article information


Submitted
04 Apr 2018
Accepted
21 May 2018
First published
21 May 2018

Chem. Commun., 2018,54, 6153-6156
Article type
Communication

A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

E. Fotopoulou, J. Martínez-Lillo, M. Siczek, T. Lis, V. Tangoulis, M. Evangelisti, E. K. Brechin and C. J. Milios, Chem. Commun., 2018, 54, 6153
DOI: 10.1039/C8CC02583E

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