Issue 41, 2018
From the journal:

Chemical Communications

The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes†

Takumi Nakazato,a   Takuto Kamatsuka,a   Junichi Inoue,b   Tsuneaki Sakurai, ORCID logo b   Shu Seki, ORCID logo b   Hiroshi Shinokubo ORCID logo a  and  Yoshihiro Miyake ORCID logo *a  

* Corresponding authors

a Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
E-mail: miyake@chembio.nagoya-u.ac.jp

b Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

The reductive aromatization of naphthalene diimide provides tetrapivaloxy-2,7-diazapyrene, which serves as a versatile platform toward peripherally substituted 2,7-diazapyrenes. Time-resolved microwave conductivity measurements demonstrated that the intrinsic electron mobility of 2,7-diazapyrene is significantly higher than that of the corresponding pyrene.

Graphical abstract: The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes

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Article information

DOI
https://doi.org/10.1039/C8CC01937A
Article type
Communication
Submitted
10 Mar 2018
Accepted
05 Apr 2018
First published
06 Apr 2018

Chem. Commun., 2018,54, 5177-5180

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The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes

T. Nakazato, T. Kamatsuka, J. Inoue, T. Sakurai, S. Seki, H. Shinokubo and Y. Miyake, Chem. Commun., 2018, 54, 5177 DOI: 10.1039/C8CC01937A

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