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Issue 45, 2018
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Zeolite-templated carbons – three-dimensional microporous graphene frameworks

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Zeolite-templated carbons (ZTCs) are ordered microporous carbons synthesized by using zeolite as a sacrificial template. Unlike well-known ordered mesoporous carbons obtained by using mesoporous silica templates, ZTCs consist of curved and single-layer graphene frameworks, thereby affording uniform micropore size (ca. 1.2 nm), developed microporosity (∼1.7 cm3 g−1), very high surface area (∼4000 m2 g−1), good compatibility with chemical modification, and remarkable softness/elasticity. Thus, ZTCs have been used in many applications such as hydrogen storage, methane storage, CO2 capture, liquid-phase adsorption, catalysts, electrochemical capacitors, batteries, and fuel cells. Herein, the relevant research studies are summarized, and the properties as well as the performances of ZTCs are compared with those of other materials including metal–organic frameworks, to elucidate the intrinsic advantages of ZTCs and their future development.

Graphical abstract: Zeolite-templated carbons – three-dimensional microporous graphene frameworks

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Publication details

The article was received on 10 Mar 2018, accepted on 09 Apr 2018 and first published on 10 Apr 2018

Article type: Feature Article
DOI: 10.1039/C8CC01932K
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Chem. Commun., 2018,54, 5648-5673

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    Zeolite-templated carbons – three-dimensional microporous graphene frameworks

    H. Nishihara and T. Kyotani, Chem. Commun., 2018, 54, 5648
    DOI: 10.1039/C8CC01932K

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