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Issue 34, 2018
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Evidence for anion-binding of all-cis hexafluorocyclohexane in solution and solid state

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Abstract

We report a solution NMR and X-ray crystallographic study on the anion affinity of all-cis 1,2,3,4,5,6-hexafluorocyclohexane, which has only recently become synthetically accessible. Our results suggest that the interaction exhibits preferential 1 : 1 stoichiometry, while its strength is only moderate (e.g. Ka = 400 M−1 in acetone for Cl) and depends mainly on the size of the anion and the dielectric constant of the solvent.

Graphical abstract: Evidence for anion-binding of all-cis hexafluorocyclohexane in solution and solid state

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Article information


Submitted
05 Mar 2018
Accepted
05 Apr 2018
First published
05 Apr 2018

Chem. Commun., 2018,54, 4353-4355
Article type
Communication

Evidence for anion-binding of all-cis hexafluorocyclohexane in solution and solid state

O. Shyshov, K. A. Siewerth and M. von Delius, Chem. Commun., 2018, 54, 4353 DOI: 10.1039/C8CC01797B

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