Issue 40, 2018
From the journal:

Chemical Communications

Argentate(i) and (iii) complexes as intermediates in silver-mediated cross-coupling reactions†

Sebastian Weske,‡a   Richard A. Hardin,‡b   Thomas Auth,‡a   Richard A. J. O’Hair, ORCID logo *ac   Konrad Koszinowski ORCID logo *a  and  Craig A. Ogle ORCID logo *b  

* Corresponding authors

a Institut für Organische und Biomolekulare Chemie, Universität Göttingen, Tammannstraße 2, 37077 Göttingen, Germany
E-mail: konrad.koszinowski@chemie.uni-goettingen.de

b Department of Chemistry, University of North Carolina-Charlotte, Charlotte NC 28223, USA
E-mail: cogle@uncc.edu

c School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, University of Melbourne, 30 Flemington Rd, Parkville, Victoria 3010, Australia
E-mail: rohair@unimelb.edu.au

Abstract

Despite the potential of silver to mediate synthetically valuable cross-coupling reactions, the operating mechanisms have remained unknown. Here, we use a combination of rapid-injection NMR spectroscopy, electrospray-ionization mass spectrometry, and quantum chemical calculations to demonstrate that these transformations involve argentate(I) and (III) complexes as key intermediates.

Graphical abstract: Argentate(i) and (iii) complexes as intermediates in silver-mediated cross-coupling reactions

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Article information

DOI
https://doi.org/10.1039/C8CC01707G
Article type
Communication
Submitted
01 Mar 2018
Accepted
16 Apr 2018
First published
30 Apr 2018
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2018,54, 5086-5089

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Argentate(I) and (III) complexes as intermediates in silver-mediated cross-coupling reactions

S. Weske, R. A. Hardin, T. Auth, R. A. J. O’Hair, K. Koszinowski and C. A. Ogle, Chem. Commun., 2018, 54, 5086 DOI: 10.1039/C8CC01707G

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