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Issue 31, 2018
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Double spin transition in a two dimensional Fe(II) coordination network

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Abstract

In the two dimensional network [Fe(ebbtr)2(CH3CN)2](ClO4)2·4CH3CN a sequence of LS → HS → LS → HS transitions occurs as the exclusive result of the change in temperature. This property results from the extraordinary flexibility/elasticity manifested in the hierarchical arrangement of structural events involving the reorientation of coordinated/noncoordinated molecules as well as with the deformation and the mutual shift of the polymeric units.

Graphical abstract: Double spin transition in a two dimensional Fe(ii) coordination network

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Publication details

The article was received on 27 Feb 2018, accepted on 21 Mar 2018 and first published on 22 Mar 2018


Article type: Communication
DOI: 10.1039/C8CC01621F
Citation: Chem. Commun., 2018,54, 3895-3898
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    Double spin transition in a two dimensional Fe(II) coordination network

    M. Weselski, M. Książek, D. Rokosz, A. Dreczko, J. Kusz and R. Bronisz, Chem. Commun., 2018, 54, 3895
    DOI: 10.1039/C8CC01621F

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