Issue 42, 2018

Layer-sliding-driven crystal size and photoluminescence change in a novel SCC-MOF

Abstract

A novel silver-chalcogenolate cluster-based framework Ag12TPPA·AA with long-lived afterglow was successfully synthesized. It transformed into more densely packed Ag12TPPA·AB and Ag12TPPA·ABC by layer sliding accompanied by macroscopic crystal contraction and changing luminescence.

Graphical abstract: Layer-sliding-driven crystal size and photoluminescence change in a novel SCC-MOF

Supplementary files

Article information

Article type
Communication
Submitted
25 Feb 2018
Accepted
30 Apr 2018
First published
01 May 2018

Chem. Commun., 2018,54, 5361-5364

Layer-sliding-driven crystal size and photoluminescence change in a novel SCC-MOF

X. Du, B. Yan, J. Wang, X. Xi, Z. Wang and S. Zang, Chem. Commun., 2018, 54, 5361 DOI: 10.1039/C8CC01559G

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