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Issue 50, 2018
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Site-selectivity in the halogenation of titanium-functionalized polyoxovanadate–alkoxide clusters

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Abstract

Herein, we report the synthesis and characterization of a dititanium-functionalized polyoxovanadate–alkoxide cluster. The incorporation of a second heterometal within the cluster core results in striking differences in reactivity of the multimetallic complex. Chlorination of the metal oxide cluster is reported, revealing the directing role of titanium in M–O bond cleavage.

Graphical abstract: Site-selectivity in the halogenation of titanium-functionalized polyoxovanadate–alkoxide clusters

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Submitted
23 Feb 2018
Accepted
20 Apr 2018
First published
20 Apr 2018

Chem. Commun., 2018,54, 6839-6842
Article type
Communication

Site-selectivity in the halogenation of titanium-functionalized polyoxovanadate–alkoxide clusters

L. E. VanGelder, P. L. Forrestel, W. W. Brennessel and E. M. Matson, Chem. Commun., 2018, 54, 6839
DOI: 10.1039/C8CC01517A

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