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Issue 33, 2018

Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

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Abstract

Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

Graphical abstract: Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

Supplementary files

Article information


Submitted
16 Feb 2018
Accepted
28 Mar 2018
First published
29 Mar 2018

Chem. Commun., 2018,54, 4148-4151
Article type
Communication
Author version available

Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

B. Gu, C. Sun, J. C. Fettinger, W. H. Casey, A. Dikhtiarenko, J. Gascon, K. Koichumanova, K. Babu Sai Sankar Gupta, H. Jan Heeres and S. He, Chem. Commun., 2018, 54, 4148 DOI: 10.1039/C8CC01363B

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