Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

Ashish Singh; Syamantak Roy; Chayanika Das; Debabrata Samanta; Tapas Kumar Maji

doi:10.1039/C8CC01291A

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Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis†

Ashish Singh,

^a Syamantak Roy,

^a Chayanika Das,

^a Debabrata Samanta

^a and Tapas Kumar Maji

*^a

Author affiliations

* Corresponding authors

^a Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore-560064, India
E-mail: tmaji@jncasr.ac.in
Tel: +91-8022082826

Abstract

We report the design and synthesis of two Co²⁺ and Zn²⁺ phthalocyanine (PC)-based redox active metal–organic conjugated microporous polymers (MO-CMP), CoCMP and ZnCMP, respectively, obtained by a Schiff base condensation reaction. CoCMP, where Co²⁺ is stabilized by N4-coordination of PC, has shown stable and efficient electrocatalytic activity towards the OER with a low overpotential of 340 mV.

This article is part of the themed collection: 20th Anniversary of the CRSI: Celebrating Indian Chemistry in ChemComm

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Article information

DOI: https://doi.org/10.1039/C8CC01291A
Article type: Communication
Submitted: 13 Feb 2018
Accepted: 27 Mar 2018
First published: 29 Mar 2018

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Chem. Commun., 2018,54, 4465-4468

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Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

A. Singh, S. Roy, C. Das, D. Samanta and T. K. Maji, Chem. Commun., 2018, 54, 4465 DOI: 10.1039/C8CC01291A

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Chemical Communications

Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis†

Abstract

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Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

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