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Issue 53, 2018
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Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional framework

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Abstract

A rylene annulated phthalocyanine (ZnPcPDI4) was designed and synthesized. Single-crystal X-ray diffraction analyses unambiguously confirmed the giant molecule quasi-planar “four leaf clover” skeleton with a 27 Å diameter and a two-dimensional cage-like supramolecular structure. The fully conjugated characteristics endowed it with significant Q-band red-shifts to the near-infrared region of 785 nm, and a largely degenerated LUMO level.

Graphical abstract: Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional framework

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Publication details

The article was received on 11 Feb 2018, accepted on 21 Apr 2018 and first published on 23 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01216D
Citation: Chem. Commun., 2018,54, 7294-7297
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    Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional framework

    J. Feng, L. Fu, T. Huang, H. Geng, W. Jiang and Z. Wang, Chem. Commun., 2018, 54, 7294
    DOI: 10.1039/C8CC01216D

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