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Issue 27, 2018
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Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes

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Abstract

Turning on the fluorescence of [3]cumulenes: we report the luminescence at room temperature upon aggregation of [3]cumulenes functionalized with propeller-like heptagon-containing polyphenylenes. These endgroups turn on the emission of a [3]cumulene by steric protection and restriction of their intramolecular rotations in the aggregates.

Graphical abstract: Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes

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Supplementary files

Article information


Submitted
16 Jan 2018
Accepted
05 Mar 2018
First published
06 Mar 2018

Chem. Commun., 2018,54, 3359-3362
Article type
Communication

Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes

V. G. Jiménez, R. Tapia, M. A. Medel, I. F. A. Mariz, T. Ribeiro, V. Blanco, J. M. Cuerva, E. Maçôas and A. G. Campaña, Chem. Commun., 2018, 54, 3359
DOI: 10.1039/C8CC00386F

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