Issue 26, 2018
From the journal:

Chemical Communications

Coupling photo-, mechano- and thermochromism and single-ion-magnetism of two mononuclear dysprosium–anthracene–phosphonate complexes†

Xin-Da Huang,a   Mohamedally Kurmoo,b   Song-Song Bao,a   Kun Fan,a   Yan Xu,a   Zhao-Bo Hua  and  Li-Min Zheng ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, P. R. China
E-mail: lmzheng@nju.edu.cn

b Institue deChimie de Strasbourg, CNRS-UMR7177, Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg Cedex 67007, France

Abstract

DyIII(depma)3(NO3)3 (1) and DyIII(depma)4(NO3)2(CF3SO3) (2) differ structurally by the number of depma ligands and the supramolecular interactions (π–π and C–H⋯π, respectively) between anthracene moieties. They exhibit single-ion-magnetism which is coupled to photo- and mechanochromism that are partially reversible by thermal annealing. The changes are associated with the formation and destruction of excimers.

Graphical abstract: Coupling photo-, mechano- and thermochromism and single-ion-magnetism of two mononuclear dysprosium–anthracene–phosphonate complexes

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Article information

DOI
https://doi.org/10.1039/C8CC00220G
Article type
Communication
Submitted
10 Jan 2018
Accepted
04 Mar 2018
First published
06 Mar 2018

Chem. Commun., 2018,54, 3278-3281

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Coupling photo-, mechano- and thermochromism and single-ion-magnetism of two mononuclear dysprosium–anthracene–phosphonate complexes

X. Huang, M. Kurmoo, S. Bao, K. Fan, Y. Xu, Z. Hu and L. Zheng, Chem. Commun., 2018, 54, 3278 DOI: 10.1039/C8CC00220G

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