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Issue 13, 2018
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Relay photocatalytic cascade reactions: synthesis of indolo[2,1-a]isoquinoline derivatives via double C(sp3)–H bond functionalization

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Abstract

A relay photoredox catalysis strategy concomitant with [1,5] hydrogen atom transfer has been applied in the construction of a biologically important indolo[2,1-a]isoquinoline framework via a cascade reaction. This reaction enables double C(sp3)–H bond functionalization and formation of two carbon–carbon double bonds from readily available starting materials in an efficient and step-economical manner.

Graphical abstract: Relay photocatalytic cascade reactions: synthesis of indolo[2,1-a]isoquinoline derivatives via double C(sp3)–H bond functionalization

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Article information


Submitted
26 Dec 2017
Accepted
21 Jan 2018
First published
22 Jan 2018

Chem. Commun., 2018,54, 1655-1658
Article type
Communication

Relay photocatalytic cascade reactions: synthesis of indolo[2,1-a]isoquinoline derivatives via double C(sp3)–H bond functionalization

J. Cheng, J. Xie and C. Zhu, Chem. Commun., 2018, 54, 1655
DOI: 10.1039/C7CC09820K

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