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Issue 31, 2018
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Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction

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Abstract

The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(II) complex. This metal complex can be protonated or deprotonated reversibly in situ to switch on or off the photocatalytic performance towards CO2 reduction. The O substituent appears essential for catalysis.

Graphical abstract: Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction

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Supplementary files

Article information


Submitted
11 Dec 2017
Accepted
13 Mar 2018
First published
13 Mar 2018

Chem. Commun., 2018,54, 3819-3822
Article type
Communication
Author version available

Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction

D. B. Burks, S. Davis, R. W. Lamb, X. Liu, R. R. Rodrigues, N. P. Liyanage, Y. Sun, C. E. Webster, J. H. Delcamp and E. T. Papish, Chem. Commun., 2018, 54, 3819
DOI: 10.1039/C7CC09507D

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